Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 80, Issue 18, Pages 9365-9369Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.5b01850
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Funding
- MEXT
- JSPS
- Grants-in-Aid for Scientific Research [15H05850, 26248031] Funding Source: KAKEN
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A photocatalytic synthesis of homoallyl ketones was achieved via a one-pot procedure starting from a Norrish Type I reaction of cyclopentanones, followed by a decatungstate-catalyzed hydroacylation of electron-deficient olefins by the resulting 4-pentenals. The site-selective formyl H-abstraction in the second step can be explained by radical polar effects in the transition state.
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