Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 80, Issue 12, Pages 6400-6410Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.5b00846
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Funding
- CSIR New Delhi (Network Project) [ORIGIN-CSC0108]
- CSIR-India
- NIPER-Kolkata
- UGC-India
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The broad applicability of the hitherto unexplored reagent combination PPh3 center dot HBr-DMSO is exemplified with multiple highly diverse one-step transformations to synthetically useful building blocks, such as flavones, 4H-thiochromen-4-ones, alpha-hydroxy ketones, 1,4-naphthoquinones (including vitamin K-3), 2-bromo-3-substituted-1H-1-indenones, 2-rnethylthio-1H-1-indenones, 3-butyne-1,2-dione, and 4-pentene-2,3-diones. The simple and mild reaction conditions make the reagent superior in terms of yield and substrate scope in comparison with the existing alternatives.
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