Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 80, Issue 9, Pages 4392-4397Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.5b00240
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Funding
- Royal Institute of Technology
- National Institutes of Health [R01GM080295]
- National Science Foundation [CHE-1112436]
- China Scholarship Council
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1112436] Funding Source: National Science Foundation
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A metal-free method for fast and clean anilide formation from perfluoroaryl azide and thioacid is presented. The reaction proved highly efficient, displaying fast kinetics, high yield, and good chemoselectivity. The transformation was compatible with various solvents and tolerant to a wide variety of functional groups, and it showed high performance in polar protic/aprotic media, including aqueous buffer systems.
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