Journal
DESALINATION
Volume 272, Issue 1-3, Pages 46-50Publisher
ELSEVIER
DOI: 10.1016/j.desal.2010.12.051
Keywords
Multi-wall carbon nanotubes; Aromatic polyamide; Nanocomposite membrane; Reinforcement; Water treatment
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Funding
- Div Of Biological Infrastructure
- Direct For Biological Sciences [830093] Funding Source: National Science Foundation
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Multi-wall carbon nanotube (MWCNT)/aromatic polyamide (PA) nanocomposite membranes were synthesized by a polymer grafting process. Surface morphology, roughness, and mechanical strength of the resultant nanocomposite membranes were characterized by scanning electron microscopy (SEM), atomic force microscopy (AFM), and micro-strain analysis, respectively. SEM and AFM images showed that MWCNTs were well dispersed in the PA matrix. Measurements of mechanical properties of this composite showed increasing membrane strength with increasing MWCNT content with monotonic increases in Young's modulus, toughness, and tensile strength. The addition of MWCNTs also improved the rejection of both salt and organic matter relative to the 10% PA membrane base case. The nanocomposite membrane synthesized with 15 mg/g MWCNT in a 10% PA casting solution rejected NaCl and humic acid by factors of 3.17 and 1.67 respectively relative to the PA membrane without MWCNTs, while membrane permeability decreased by 6.5%. (C) 2011 Elsevier B.V. All rights reserved.
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