Adsorption of basic dyes on activated carbon prepared from Polygonum orientale Linn: Equilibrium, kinetic and thermodynamic studies

Low cost activated carbon was prepared from Polygonum orientale Linn by phosphoric acid activation. Its ability to remove the basic dyes, malachite green (MG) and rhodamine B (RB) was evaluated. The surface area of P. orientale Linn activated carbon (PLAC) was found to be 1398 m(2)/g. The effects of experimental parameters such as initial concentration, contact time, pH, ionic strength and temperature on the adsorption were investigated. Alkaline pH was more favorable for MG adsorption, whereas acidic pH was better for RB uptake. Adsorption of dyes on PLAC was weakly dependent on ionic strength. The adsorption kinetics was found to be best represented by the pseudo-second-order kinetic model. The mechanism of the adsorption process was determined from the intraparticle diffusion model. The equilibrium adsorption data was well described by the Langmuir model. Thermodynamic study showed that the adsorption was a spontaneous, endothermic process. (C) 2009 Elsevier BM. All rights reserved.