Journal
DENTAL MATERIALS JOURNAL
Volume 29, Issue 4, Pages 438-445Publisher
JAPANESE SOC DENTAL MATERIALS DEVICES
DOI: 10.4012/dmj.2010-017
Keywords
Hydroxyapatite formation; SAM surfaces; Surface plasmon resonance
Funding
- Ministry of Education, Science, Sports and Culture of Japan [18390515]
- Grants-in-Aid for Scientific Research [18390515] Funding Source: KAKEN
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Hydroxyapatite formation was examined at the surface of self-assembled monolayers (SAMs) modified with four functional groups, -COOH, -NH2, and -OH. For COOH-SAM and NH2-SAM, scanning electron spectroscopic observation showed that flake-like sheet crystals covered the whole wafer and small broccoli-like crystals were observed occasionally on the flake-like crystal base layer. For CH3-SAM and OH-SAM, no flake-like sheet crystals were observed; broccoli-like crystals were observed in a dispersed manner for CH3-SAM, but in localized spots for OH-SAM. X-ray diffraction patterns showed a strong apatite pattern oriented toward the c-axis direction for COOH-SAM. ESCA analysis revealed distinct Ca, P, O peaks for COOH-, NH2-, CH3-, and OH-SAM. Surface plasmon resonance (SPR) analysis indicated that during the supply of supersaturated calcium phosphate solution, the deposition of precipitates increased monotonically with time for COOH-SAM, increased slightly for NH2-SAM, but little increase in deposition was detected for CH3-SAM and OH-SAM.
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