4.7 Article

Hydrazone-based covalent organic frameworks for Lewis acid catalysis

Journal

DALTON TRANSACTIONS
Volume 47, Issue 39, Pages 13824-13829

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c8dt03005g

Keywords

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Funding

  1. National University of Singapore [CENGas R-261-508-001-646]
  2. Ministry of Education - Singapore (MOE AcRF Tier 1) [R-279-000-472-112, R-279-000-540-114]
  3. Agency for Science, Technology and Research [PSF 1521200078, IRG A1783c0015]

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Hydrazone-based covalent organic frameworks (COFs) are rich in functional groups but have very limited variety and applications. Herein, two hydroxy-rich hydrazone-based COFs are synthesized in pure water and postsynthetically incorporated with Co-II, exhibiting Lewis acid catalytic activity towards cyanosilylation of various aldehydes with size selectivity.

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