Mg-Al hydrotalcite-supported Pd catalyst for low-temperature CO oxidation: effect of Pdn+ species and surface hydroxyl groups

Hydrotalcite-like compounds (HTlcs) are promising supports or catalyst precursors for heterogeneous catalysts. Herein, MgAl-HTlcs-supported Pd catalyst was fabricated, and two Pd catalysts supported on Mg(OH)(2) and Al(OH)(3) were prepared for comparison. The presence of hydroxyl groups (OH-) in the support is important for obtaining uniform Pd nanoparticles with small sizes. We found that Pdn+ species are more active than Pd-0 in low temperature CO oxidation due to their lower barrier in CO activation. The Pd/MgAl-HT catalyst shows the most stable Pdn+ at a temperature lower than 90 degrees C, leading to the highest catalytic activity towards CO oxidation. Pdn+ in the Pd/Al(OH)(3) catalyst is more stable than that in Pd/Mg(OH)(2) at low temperature, which is ascribed to its smaller temperature hysteresis (T-hysteresis) between the oxidation and re-reduction cycles. The effect of hydroxyl groups on stabilizing Pd species is related to the stability of Pd catalyst in CO oxidation reaction.