Journal
DALTON TRANSACTIONS
Volume 43, Issue 10, Pages 3835-3838Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3dt53336k
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Funding
- NSAF [11076018]
- Sichuan Province Science and Technology Support Programme [2011FZ0048]
- Doctoral Program of the Ministry of Education of China [20130181110023]
- National Science Foundation for Fostering Talents in Basic Research of the National Natural Science Foundation of China [J1210004, J1103315]
- Analytical & Testing Center of College of Chemistry for HRESI-MS
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Pillar[5] arenes, as a new intriguing class of calixarene analogues, were functionalized with ten diglycolamide (DGA) arms on both sides (rims) of the pillar framework and evaluated for their extraction behaviour towards Am(III) and Eu(III). These novel extractants exhibit excellent separation and extraction efficiency, suggesting its significant potential for nuclear waste remediation. Laser induced fluorescence experiments disclosed strong complexation of the trivalent metal ions with the pillararene-DGA ligands.
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