Journal
DALTON TRANSACTIONS
Volume 43, Issue 15, Pages 5639-5642Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3dt53251h
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Funding
- 973 Program [2012CB821702, 2011CB935902]
- NSFC [91122004, 21271137]
- 111 project [B12015]
- NSF of Tianjin [11JCYBJC03500]
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Triple core-shell structures in the Cu24Gd6 and Cu24Dy6 clusters were first observed and structurally characterized. The magnetic investigations reveal that Cu24Gd6 possesses the significant magnetic entropy change (-Delta S-m) of 21.2 J kg(-1) K-1 for Delta H = 7 T, and a slow magnetization relaxation is observed in Cu24Dy6.
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