Journal
DALTON TRANSACTIONS
Volume 43, Issue 17, Pages 6300-6303Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4dt00287c
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Funding
- U.S. Department of Energy, Office of Science, Early Career Research Program [DE-SC0006518]
- Research Corporation for Science Advancement (Cottrell Sholar Award)
- University of Pennsylvania
- U. S. National Science Foundation [CHE-0840438]
- U.S. Department of Energy (DOE) [DE-SC0006518] Funding Source: U.S. Department of Energy (DOE)
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An electron rich, air-stable hydroxylamine ligand and a strongly stabilized cerium(IV) hydroxylaminato complex are described. The synthesis of Ce[eta 2-ON(Bu-t)(2-OMe-5-Bu-t-C6H3)](4) (1) proceeded through a one pot protonolysis and oxidation procedure. Complex 1 crystallized with the molecule in exact S-4 symmetry. The hydroxylaminato ligands were bound in an eta 2 mode that is of interest for potential application in the separations chemistry of rare earth metals.
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