4.7 Article

Structural modulation in two CuII-based MOFs by synergistic assembly involving the mixed-ligand synthetic strategy and the solvent effect

Journal

DALTON TRANSACTIONS
Volume 43, Issue 42, Pages 15708-15712

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4dt02321h

Keywords

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Funding

  1. NNSF of China [21403102, 21271097, 21031002, 21371102]
  2. NSF of Shandong Province [ZR2012BQ023]
  3. Liaocheng University Start-up Fund for Doctoral Scientific Research [31805]

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Two Cu-II-based MOFs have been constructed by synergistic assembly involving the mixed-ligand synthetic strategy and the solvent effect. Compound 1 is a 3D structure and represents a cds topology, while compound 2 displays a rare structure built by three distinct {Cu-4} clusters as SBUs. Moreover, the magnetic properties of 2 have been thoroughly investigated.

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