Journal
DALTON TRANSACTIONS
Volume 43, Issue 46, Pages 17296-17302Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4dt01954g
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Funding
- National Natural Science Foundation of China (NSFC) [21225103, 21221062, 21301105, 21471087]
- Beijing Natural Science Foundation [2144051]
- Specialized Research Fund for the Doctoral Program of Higher Education of China
- Tsinghua University Initiative Foundation Research Program
- THSJZ
- open project of the Key Laboratory of Polyoxometalate Science of the Ministry of Education of China
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Three single-sided, triol-functionalized Anderson POM hybrids were successfully synthesized. With suitable solvents and the effect driven by common-ion synergy, enantiopure crystals were obtained when the spontaneous resolution of enantiomers occurred upon crystallization. The chirality of POM-organic hybrids was confirmed by single-crystal X-ray diffraction and solid-state CD spectrum. A reversible, spontaneous resolution process for POM-based inorganic-organic hybrids was observed in this work.
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