4.7 Article

A highly emissive inorganic hexamolybdenum cluster complex as a handy precursor for the preparation of new luminescent materials

Journal

DALTON TRANSACTIONS
Volume 43, Issue 16, Pages 6021-6025

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3dt53126k

Keywords

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Funding

  1. Marie Curie Intra-European Fellowship (project PolyMoRe) [327440]
  2. Russian Foundation for Basic Research [12-03-31670, 14-04-01816]
  3. Japan Society for the Promotion of Science (JSPS)
  4. Grants-in-Aid for Scientific Research [26248022, 25620035] Funding Source: KAKEN

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The synthesis and characterisation of a new, highly luminescent inorganic cluster complex, (Bu4N)(2)[Mo6I8(NO3)(6)], are described. The complex possesses labile nitrato ligands and is therefore a useful precursor for the design of new luminescent materials. To exemplify this, functionalised polystyrene beads have been utilised as polymeric ligands to immobilise the molybdenum cluster complex.

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