Journal
DALTON TRANSACTIONS
Volume 43, Issue 4, Pages 1550-1563Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3dt51594j
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Funding
- Research Council of Hakim Sabzevari University
- Research Council of Shahid Beheshti University
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A novel magnetic inorganic-organic nanohybrid material H6P2W18O62/pyridino-Fe3O4 (HPA/TPI-Fe3O4) was fabricated and performed as an efficient, eco-friendly, and highly recyclable catalyst for the solvent-free, one-pot, and multi-component synthesis of various substituted 1-amidoalkyl-2-naphthols from the reaction of beta-naphthol, an aldehyde, and benzamide with good to excellent yields (47-94%) and in a short span of time (25-60 min). The nanohybrid catalyst was prepared by the chemical anchoring of Wells-Dawson heteropolyacid H6P2W18O62 onto the surface of modified Fe3O4 nanoparticles with N-[3-(triethoxysilyl)propyl]isonicotinamide (TPI) linker. The magnetically recoverable catalyst was easily recycled at least eight times without any loss of catalytic activity. XRD, TEM, UV-vis, and FTIR confirmed that the heteropolyacid H6P2W18O62 is well dispersed on the surface of the solid support and its structure is retained after immobilization on the pyridine modified Fe3O4 nanoparticles. This protocol is developed as a safe and convenient alternate method for the synthesis of 1-amidoalkyl-2-naphthols utilizing an eco-friendly, and a highly reusable catalyst.
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