4.7 Article

Step-by-step covalent modification of Cr-templated Anderson-type polyoxometalates

Journal

DALTON TRANSACTIONS
Volume 43, Issue 23, Pages 8587-8590

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4dt00033a

Keywords

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Funding

  1. National Science Foundation of China [21222104]
  2. EPSRC [EP/H024107/1, EP/I033459/1, EP/J015156/1]
  3. Fundamental Research Funds for the Central Universities [RC1302]
  4. Royal-Society Wolfson Foundation
  5. University of Glasgow
  6. Engineering and Physical Sciences Research Council [EP/J015156/1, EP/H024107/1] Funding Source: researchfish

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A series of tripodal alcohols substituted Anderson-type polyoxometalates (POMs) including mono-substituted (compounds 1 and 2), asymmetrical bi-substituted (compound 3), and symmetrical bi-substituted ones (compounds 4 and 5) have been synthesized under hydrothermal conditions using a pre-designed step-by-step strategy, and compounds 1, 2 and 4 have been fully characterized by single-crystal X-ray diffraction, ESI-MS, and elemental analysis.

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