Journal
DALTON TRANSACTIONS
Volume 43, Issue 25, Pages 9431-9437Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4dt00157e
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Funding
- Department of Science and Technology (DST), New Delhi-110016 (India), for the Ramanna Fellowship
- CSIR for a SRF fellowship
- NSF-MRI program [CHE1039027]
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The synthesis and the first X-ray structural characterization of a selenenyl selenocyanate, [o-(2,6-diisopro-pylphenyliminomethinyl)phenyl]selenenyl selenocyanate (DiPhSeSeCN), with a stable Se-Se bond are described. The isolation of stable DiPhSeSeCN, both in the solid state and in solution, is facilitated by strong intramolecular Se center dot center dot center dot N interaction. The compound DiPhSeSeCN, an example of unsymmetrical diselenide, did not exhibit any glutathione peroxidase-like activity. The reaction of DiPhSeSeCN with thiophenol afforded (3H-benzo[c][1,2] diselenol-3-yl)(phenyl) sulfane.
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