Journal
DALTON TRANSACTIONS
Volume 43, Issue 5, Pages 1961-1964Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3dt53229a
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Funding
- Swiss National Science Foundation
- University of Basel
- European Union (CELLO) [STRP 248043]
- European Research Council [267816 LiLo]
- Spanish Ministry of Economy and Competitiveness (MINECO)
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Small quantities of Cl- ions result in dramatic reductions in the performance of ionic transition metal complexes in light-emitting electrochemical cells. Strong ion-pairing between aromatic protons and chloride has been established in both the solid state and solution. X-ray structural determination of 2{[Ir(ppy)(2)(bpy)][Cl]}center dot 2CH(2)Cl(2)center dot[H3O]center dot Cl reveals the unusual nature of an impurity encountered in the preparation of [Ir(ppy)(2)(bpy)][PF6].
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