4.7 Article

Tetrahedral tetrazolate frameworks for high CO2 and H2 uptake

Journal

DALTON TRANSACTIONS
Volume 43, Issue 8, Pages 3210-3214

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3dt53269k

Keywords

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Funding

  1. NSFC [21221001, 21103189, 21173224, 91222105]
  2. Youth Innovation Promotion Association of CAS
  3. [2011CB932504]
  4. [2012CB821705]

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Three tetrahedral tetrazolate frameworks with two different 4-connected topologies including lonsdaleite (lon, for 1) and diamond (dia, for 2 and 3) have been synthesized, and the lon-type framework with high CO2 and H-2 uptake capacity can irreversibly transform to the dia-type framework via solvent-exchange.

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