Journal
DALTON TRANSACTIONS
Volume 42, Issue 26, Pages 9437-9443Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3dt50987g
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- National University of Singapore
- Ministry of Education
- Institute of Materials Research and Engineering, A*STAR, Singapore [R143-000-426-305]
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Two novel pyridyl and thioether hybridised 1,2,3-triazole ligands 1-(2-picolyl)-4-(2-(methylthio)-pyridine)-1H-1,2,3-triazole (L1) and 1-(4-picolyl)-4-(2-(methylthio)-pyridine)-1H-1,2,3-triazole (L2) were prepared from CuAAC click reactions. Reactions of CuI with the ligands L1 and L2 yielded two one-dimensional coordination polymers [Cu(6)l(6)(L1)(2)](n) (1) and [Cu(2)l(2)(L2)(2)](n) (2). Single-crystal X-ray diffraction reveals that 1 and 2 are polymeric with [Cu(6)l(6)] and [Cu(2)l(2)] respectively as building blocks. Both ligands (L1 and L2) and complexes (1 and 2) are photoluminescence active. Complexes 1 and 2 are also catalytically active towards azide-alkyne cycloaddition reactions.
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