4.7 Article

Highly reactive (< 1 min) ratiometric naked eye detection of hypochlorite with real application in tap water

Journal

DALTON TRANSACTIONS
Volume 42, Issue 28, Pages 10097-10101

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3dt51238j

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Funding

  1. DST (Government of India)
  2. CSIR (Government of India)
  3. UGC
  4. CSIR

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The de-diaminomaleonitrile reaction in a simple carbazole diaminomaleonitrile hybrid (CDH) was promoted by OCl- which disrupted the ICT mechanism by breaking the donor and acceptor linkage. This system utilized an irreversible OCl- promoted oxidation reaction and it responded instantaneously at room temperature. The chemosensor also showed excellent performance in tap water and the dip-stick method.

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