Journal
DALTON TRANSACTIONS
Volume 42, Issue 29, Pages 10579-10586Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3dt50315a
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Funding
- National Natural Science Foundation of China [20901070]
- China Postdoctoral Science Foundation [20090460859]
- Zhengzhou University (P. R. China)
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A series of novel lanthanide metal-organic frameworks, namely, {[Ln(2)(L)(2)]center dot(H2O)(3)center dot(Me2NH2)(2)}(n) (Ln = La (1), Ce (2), Pr (3), Nd (4), Sm (5), Eu (6), Gd (7), Tb (8), Ho (9), Er (10)), have been synthesized with hydro(solvo) thermal conditions based on a flexible multicarboxylic acid (H4L = 5-(3,5-dicarboxybenzyloxy)isophthalic acid). Single crystal X-ray diffraction reveals that all of them are isomorphous and possess a (6,6) topological net with a Schl fli symbol of {4(8)center dot 6(7)}. Considering the blue-emission of compound 1 and the intense emission of the Eu and Tb compounds, we successfully construct isostructural Eu3+ doped Tb compounds whose color can be tuned easily by adjusting the different concentration of the doped ions, and we also obtained white light emitting materials through the doping of Eu and Tb ions in the La compounds.
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