4.7 Article

Inorganic click (iClick) synthesis of heterotrinuclear PtII/Au2I complexes

Journal

DALTON TRANSACTIONS
Volume 42, Issue 42, Pages 14963-14966

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3dt52105b

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Funding

  1. UF
  2. Petroleum Research Fund [51715-ND3]
  3. NSF [CHE-0821346]

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Metal-azide-metal-acetylide cycloaddition (iClick) reactions to synthesize heterotrimetallics and an unexpected novel tetra-nuclear gold(I) complex, are described. In addition, a discussion regarding the connection between traditional azide-alkyne cycloaddition reactions and iClick is presented focusing on applications towards linking multiple metal ions.

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