Journal
DALTON TRANSACTIONS
Volume 42, Issue 27, Pages 9818-9821Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3dt51048d
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- Russian Federation
- RFBR [12-03-00158]
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The complex [Na-4((CH3)(2)CO)(15)][PtBi2I12]center dot 3(CH3)(2)CO (1) has been prepared by the reaction of BiI3, NaI and H-2[PtCl6]center dot 6H(2)O and structurally characterized using X-ray diffractometry. It represents the first example of a polyiodobismuthate with an octahedral heterometallic unit. Interatomic interactions in the [PtBi2I12](2-) anion were characterized using the topological methods QTAIM and ELF.
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