Journal
DALTON TRANSACTIONS
Volume 42, Issue 41, Pages 14685-14688Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3dt51554k
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Funding
- Office of Science, Office of Basic Energy Sciences, of the U.S. Department of Energy [DE-AC02-05CH11231]
- Department of Energy [DE-FG02-02ER45999]
- Grants-in-Aid for Scientific Research [24108736, 24108731] Funding Source: KAKEN
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The mononuclear ferric compound Fe(H-5-Cl-thsa-Me)(5-Cl-thsa-Me)-H2O (1) was synthesized and characterized using powder/single-crystal X-ray diffraction, Mossbauer spectroscopy, differential scanning calorimetry (DSC), and magnetic susceptibility measurements. This photo-responsive compound shows reversible, two-step spin-crossover behaviour. Moreover, dielectric anomalies were observed during the spin transitions, demonstrating the multifunctional properties of compound 1.
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