Dual channel selective fluorescence detection of Al(III) and PPi in aqueous media with an 'off-on-off' switch which mimics molecular logic gates (INHIBIT and EXOR gates)

In this study, we have synthesized a simple Schiff base type isophthaloyl salicylaldehyde hydrazone (ISH) moiety which selectively detects Al(III) and PPi with a fluorescence enhancement at two different wave-lengths in aqueous solution. The sensing phenomenon is also reversible and thus the sensor beautifully mimics logic gates (INHIBIT and EXOR gates).