4.7 Article

A {Cr2Dy4} compressed octahedron: the first sulfate-based single-molecule magnet

Journal

DALTON TRANSACTIONS
Volume 42, Issue 4, Pages 867-870

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2dt32651e

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Funding

  1. Natural Science Foundation of China [21071099]
  2. Guangdong Province Universities and Colleges High Level Talent Project [2011QY01]

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A unique compressed octahedral {(Cr2Dy4III)-Dy-III} aggregate is the first sulfate-based single-molecule magnet (SMM) with U-eff/k(B) = 39.7 K and tau(0) = 2.9 x 10(-9) s. Its synthesis opens a new avenue to prepare 3d-4f coordination clusters.

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