4.7 Article

Red-light-absorbing diimine Pt(II) bisacetylide complexes showing near-IR phosphorescence and long-lived (IL)-I-3 excited state of Bodipy for application in triplet-triplet annihilation upconversion

Journal

DALTON TRANSACTIONS
Volume 42, Issue 40, Pages 14374-14379

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3dt51927a

Keywords

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Funding

  1. NSFC [21073028, 21273028]
  2. Science Foundation Ireland (SFI E.T.S. Walton Program) [11/W.1/E2061]
  3. Ministry of Education [SRFDP-20120041130005]

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Bodipy is used for the preparation of Pt(II) bisacetylide complexes which show strong absorption of visible light and long-lived triplet state. Room temperature (RT) near-IR phosphorescence of Bodipy was observed. The pi-conjugation framework of visible light-harvesting Bodipy ligand was connected to the Pt(II) center by the C C bond. The complexes were used as triplet photosensitizers for triplet-triplet annihilation (TTA) upconversion.

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