Journal
DALTON TRANSACTIONS
Volume 42, Issue 4, Pages 981-986Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2dt31940c
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A heteroditopic chemosensor 2 based on a thiacalix[4]crown with a 1,3-alternate conformation has been synthesized and shows a selective fluorescence turn-off response with Fe3+ ions in mixed aqueous media. Furthermore, the 2-Fe3+ complex can be used as a chemosensing system for the detection of Li+ and cysteine based on two different approaches. Moreover, the sequence addition of Fe3+ and Li+ triggers an Fe3+/Li+ switchable on-off-on fluorescence chemosensor with negative allosteric regulations.
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