Journal
DALTON TRANSACTIONS
Volume 42, Issue 22, Pages 7842-7845Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3dt50750e
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Funding
- NRF/MEST of Korea through CRI, GRL [2010-00353]
- WCU [R31-2008-000-10010-0]
- MEXT, Japan [20108010]
- Grants-in-Aid for Scientific Research [20108010] Funding Source: KAKEN
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The ring size effect of macrocyclic TMC ligands in nonheme iron(IV)-oxo complexes has been examined in hydrogen atom transfer (HAT) and oxygen atom transfer (OAT) reactions; an iron(IV)-oxo complex bearing a smaller TMC ligand is more reactive in both HAT and OAT reactions, resulting from its high Fe-IV/III redox potential.
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