4.7 Article

A luminescent single-molecule magnet: observation of magnetic anisotropy using emission as a probe

Journal

DALTON TRANSACTIONS
Volume 42, Issue 6, Pages 1987-1990

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2dt32785f

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Funding

  1. Ministry of Education, Culture, Science, Sports and Technology, Japan [20224015, 23350067, 22550053]
  2. Grants-in-Aid for Scientific Research [23550076, 23750222] Funding Source: KAKEN

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An assemblage of a Tb(III) ion and two mononuclear [Zn-II(L)] complexes as antenna chromophores (H2L: Schiff base ligand) afforded a luminescent single-molecule magnet. The f-f emission spectrum had partially resolved fine structure which provides detailed information on the magnetic anisotropy of the F-7(6) ground multiplet of the Tb(III) ion.

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