Journal
DALTON TRANSACTIONS
Volume 42, Issue 30, Pages 10964-10970Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3dt51123e
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Funding
- DST, India [SR/FT/CS-014/2008]
- IISER, Pune
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Two polymorphic 2D-coordination polymers of composition [ZnL(HCO2)](infinity) were synthesized from an in situ generated ligand [PO2((NHPy)-Py-4)(2)](-) (L-). The ligand L- was generated by a facile metal-assisted P-N bond hydrolysis reaction from the corresponding phosphonium salt 1, [P((NHPy)-Py-4)(4)]Cl, or from the neutral phosphoric triamide 2, [PO((NHPy)-Py-4)(3)]. The de-solvated sample of the polymer [ZnL(HCO2)](infinity) features polar micropores and shows a type I isotherm for CO2 sorption whereas a type II behaviour was observed for N-2. The vapour sorption isotherm of the de-solvated sample of [ZnL(HCO2)](infinity) shows preferential adsorption of water vapour over aliphatic alcohols.
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