4.7 Article

Phase transformation of ultrathin nanowires through lanthanide doping: from InOOH to rh-In2O3

Journal

DALTON TRANSACTIONS
Volume 42, Issue 13, Pages 4361-4364

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3dt32929a

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Funding

  1. National Natural Science Foundation of China [21043005, 21273080]
  2. China Scholarship Council
  3. CityU [7200317, 9610257]

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The effect of Gd3+ doping is harnessed to promote the phase transformation of ultrathin (2 nm) InOOH nanowires to corundum In2O3 and to stabilize the nanowires against morphological deformation. The approach described here suggests a new route toward morphology and phase control of In2O3 nanocrystals, which could be applied to prepare other nanocrystals.

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