Journal
DALTON TRANSACTIONS
Volume 42, Issue 22, Pages 7850-7853Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3dt50896j
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Funding
- Korea CCS RD Center (KCRC)
- Korea government (Ministry of Education, Science and Technology) [2012-0008901]
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A two-dimensional (2D) Zn(II) metal-organic framework with flexible aryl ether linkers and water molecules exposed to the pores was prepared. The supramolecular three-dimensional (3D) network is generated by the presence of extensive pi-pi contacts, which could be responsible for gas uptake. The water molecules and oxygen atoms from the flexible linkers create a polar environment within the integrated framework, leading to simultaneous selective CO2 adsorption and proton conductivity in the two-dimensional Zn(II) framework.
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