Journal
DALTON TRANSACTIONS
Volume 42, Issue 29, Pages 10388-10393Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3dt51211h
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- EPSRC
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Rhodium(III) complexes rarely display strong phosphorescence, in contrast to well-known iridium(III) complexes with cyclometallating ligands. This study shows how 1,3-bis(1-isoquinolyl) benzene cyclometallates to Rh(III) through (NCN)-C-boolean AND-N-boolean AND-coordination to give complexes with unprecedented phosphorescence quantum yields at room temperature. Their highly emissive Ir(III) analogues are also described.
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