Journal
DALTON TRANSACTIONS
Volume 42, Issue 4, Pages 1159-1167Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2dt32322b
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Funding
- U. S. National Science Foundation (NSF) [CHE-0747612]
- Research Corporation for Science Advancement
- University of Vermont [NSF DUE-0934714]
- NSF [CHE-0521237, CHE-1039436]
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A general, atom-economical method for the synthesis of phosphaalkenes is reported via the net coupling of primary alkyl or aryl phosphines with aryl or alkyl isocyanides at zirconium. The phosphorus-containing ligand can be liberated as the phosphaformamide from zirconium by reaction with an organic electrophile.
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