Journal
DALTON TRANSACTIONS
Volume 41, Issue 45, Pages 13795-13799Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2dt31487h
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Funding
- National Natural Science Foundation of China (NSFC) [50903072]
- Zhejiang Province Natural Science Foundation [Y4100197]
- Science Foundation of Zhejiang Sci-Tech University (ZSTU) [0901803-Y]
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This communication demonstrates a novel strategy for the selective growth of Au nanograins (AuNGs) on specific positions (tips, edges and facets) of Cu2O octahedrons to form Cu2O-Au hierarchical heterostructures. The surface energy distribution of the octahedrons generally follows the order of gamma((facets)) < gamma((edges)) < gamma((tips)) and leads to the preferential growth and evolution of the heterostructures. These novel Cu2O-Au hierarchical heterostructures show fascinating degradations of methylene blue (MB), due to the suppressed electron/hole recombination phenomena and the highly efficient light harvesting.
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