4.7 Article

Ligand-based solid solution approach to stabilisation of sulphonic acid groups in porous coordination polymer Zr6O4(OH)4(BDC)6 (UiO-66)

Journal

DALTON TRANSACTIONS
Volume 41, Issue 45, Pages 13791-13794

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2dt31195j

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Funding

  1. Grants-in-Aid for Scientific Research [23750155, 24510154] Funding Source: KAKEN

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By adopting a ligand-based solid solution approach, the sulphonic acid functional group can be successfully incorporated into a porous coordination polymer with UiO-66 structure type. Zr6O4(OH)(4)(BDC-SO3H)(1.1)(BDC)(4.9) possesses enhanced heat of adsorption for carbon dioxide and acetone compared to Zr6O4(OH)(4)(BDC)(6).

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