4.7 Article

Heteroleptic silver-containing ionic liquids

Journal

DALTON TRANSACTIONS
Volume 41, Issue 23, Pages 6902-6905

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2dt30725a

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Funding

  1. IWT-Vlaanderen
  2. KU Leuven [IDO/05/005, GOA 08/05]
  3. FWO-Flanders (research community Ionic Liquids)
  4. IWT-Flanders (SBO) [IWT 80031]
  5. IoLiTec (Heilbronn, Germany)

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The first examples of structurally characterised mixed-ligand metal-containing ionic liquids (ILs) are presented, synthesised by the use of different N-alkylimidazoles. The cations consist of two-coordinate silver(I) centres ligated by two different N-alkylimidazole ligands. It is shown that the resulting ionic liquids have lower melting points than the single ligand ILs.

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