Journal
DALTON TRANSACTIONS
Volume 41, Issue 10, Pages 2853-2861Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2dt11882c
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Funding
- NSF [CHE1026505]
- Alfred P. Sloan Foundation
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Polyoxometalate (POM)-based inorganic-organic molecular hybrid clusters have been recently recognized as good candidates to design novel multi-functional materials. Tremendous efforts have been invested in synthesizing many interesting hybrid structures with exceptional chemical and physical properties. Grafting organic ligands to the POM clusters render these functional clusters amphiphilic properties. Here we summarize the current progresses and provide some perspectives, from colloidal chemists' point of view, on the self-assembly of the amphiphilic POM-organic hybrids in solution and at interfaces, as well as the related consequent novel features such as enhanced fluorescent properties.
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