4.7 Article

Asymmetric hydrogenation of imines with a recyclable chiral frustrated Lewis pair catalyst

Journal

DALTON TRANSACTIONS
Volume 41, Issue 30, Pages 9026-9028

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2dt30536d

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Funding

  1. Excellence Initiative of the German federal government
  2. Excellence Initiative of the German state government

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A camphor based chiral phosphonium hydrido borate zwitterion was synthesised and successfully applied in the enantioselective hydrogenation of imines with selectivities up to 76% ee. The high stability of the novel chiral FLP-system enables effective recycling of the metal-free catalyst.

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