4.7 Article

Highly active zinc alkyl cations for the controlled and immortal ring-opening polymerization of epsilon-caprolactone

Journal

DALTON TRANSACTIONS
Volume 41, Issue 12, Pages 3377-3379

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2dt12336c

Keywords

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Funding

  1. Fundacao para a Ciencia e Tecnologia (FCT), Portugal [PTDC/QUI-QUI/099873/2008, SFRH/BPD/73253/2010, SFRH/BPD/44262/2008]
  2. ADEME (French Agency for energy and sustainable development)
  3. Region Alsace

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Zinc alkyl cations supported by N,N-BIAN-type bidentate ligands were found to be highly active in the immortal ROP of epsilon-caprolactone to yield narrowly disperse and chain length-controlled poly(epsilon-caprolactone), whether in solution or bulk polymerization conditions.

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