Journal
DALTON TRANSACTIONS
Volume 41, Issue 28, Pages 8509-8511Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2dt30818e
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Funding
- Major Research Plan of China [2011CB93202]
- National Science Foundation Center [21173230]
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An achiral (10,3) net three-dimensional metal-oxalato framework [Cu-2(C2O4)(3)(2-)](n) was formed by cation-templating. At around 165 K, the disorder-order transition of cation (C2H5)(3)NH+ hosted in the channel resulted in dielectric transition, and the antiferromagnetic interactions between the Jahn-Teller distorted Cu(II) through the oxalato-bridge below 165 K was enhanced.
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