4.7 Article

Dinuclear complexes of tetravalent cerium in an aqueous perchloric acid solution

Journal

DALTON TRANSACTIONS
Volume 41, Issue 24, Pages 7190-7192

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2dt12406h

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Primary aquo species of tetravalent cerium (Ce(IV)) in perchloric acid has been identified as a single oxo-bridging dinuclear complex, not a mononuclear one, by extended X-ray absorption fine structure (EXAFS) spectroscopy combined with density functional theory (DFT) calculations.

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