Journal
DALTON TRANSACTIONS
Volume 41, Issue 33, Pages 9867-9870Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2dt30451a
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Funding
- Department of Energy-Basic Energy Sciences [DE-AC02-07CH11358]
- U.S. Department of Energy's National Nuclear Security Administration [DE-AC04-94AL85000]
- Sandia National Laboratories' LDRD program
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A polyoxometalate-based {(Mn3MnIV)-Mn-III} single-molecule magnet exhibits a large axial anisotropy (D = -0.86 cm(-1)) resulting from a near-parallel alignment of Jahn-Teller axes. Its rigorous three-fold symmetry (i.e. rhombicity E -> 0) and increased intercluster separation via co-crystallization effectively hamper quantum tunnelling of the magnetization.
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