4.7 Article

A very simple method to synthesize nano-sized manganese oxide: an efficient catalyst for water oxidation and epoxidation of olefins

Journal

DALTON TRANSACTIONS
Volume 41, Issue 36, Pages 11026-11031

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2dt30553d

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Funding

  1. Institute for Advanced Studies in Basic Sciences
  2. University of Maragheh
  3. Sharif University of Technology

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Nano-sized particles of manganese oxides have been prepared by a very simple and cheap process using a decomposing aqueous solution of manganese nitrate at 100 degrees C. Scanning electron microscopy, transmission electron microscopy and X-ray diffraction spectrometry have been used to characterize the phase and the morphology of the manganese oxide. The nano-sized manganese oxide shows efficient catalytic activity toward water oxidation and the epoxidation of olefins in the presence of cerium(IV) ammonium nitrate and hydrogen peroxide, respectively.

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