Journal
DALTON TRANSACTIONS
Volume 41, Issue 14, Pages 3911-3914Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2dt11985d
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Funding
- U.S. Department of Energy Chemical Sciences, Geosciences and Biosciences Division, Office of Basic Sciences, Office of Science [DE-FG02-05ER15736]
- U.S. Department of Energy (DOE) [DE-FG02-05ER15736] Funding Source: U.S. Department of Energy (DOE)
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Reactions of the uranyl cation (UO22+) with 4-halopyridinium ions (X = Cl, Br, I) in high halide media (X' = Cl, Br) have produced six novel compounds, the structures of which have been determined by single crystal X-ray diffraction (XRD). The compounds can be divided into two categories based on the different modes of hydrogen bonding and halogen-halogen interactions present in the crystal structures, with one group showing approximately Type I halogen-halogen interactions and the second showing Type II. Presented is a discussion of the relative strengths of the interactions as a function of halogen size.
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