Journal
DALTON TRANSACTIONS
Volume 41, Issue 30, Pages 9056-9060Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2dt30374d
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Funding
- DFG [SFB/TRR 88]
- Landesgraduiertenforderung of the State of Baden-Wurttemberg
- Alexander von Humboldt Stiftung
- Fonds der Chemischen Industrie
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The heterolytic splitting of hydrogen by two types of [2.2]paracyclophane derived bisphosphines (1, 2a and 2b) in combination with tris(pentafluorophenyl) borane (3) at room temperature is described. The corresponding frustrated Lewis pairs (FLPs) exhibit different behavior in the activation of hydrogen. This results from diverse steric and electronic properties of the bisphosphines. The reactivity of the frustrated Lewis pairs was exploited in the first diastereoselective domino hydrosilylation/hydrogenation reaction catalyzed by FLPs.
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