Journal
DALTON TRANSACTIONS
Volume 41, Issue 38, Pages 11597-11607Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2dt30931a
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Funding
- National Natural Science Foundation of China [21172164]
- Key Laboratory of Organic Chemistry of Jiangsu Province
- Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)
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A series of bis(phenol)-functionalized imidazolium salts, 1,3-bis(4,6-di-R-1-2-hydroxybenzyl)-2-R-2-4,5-di-R-3-imidazolium chlorides (H3LCl)-Cl-n (R-1 = Bu-t, R-2 = R-3 = H, (H3LCl)-Cl-1, 1; R-1 = CH3, R-2 = R-3 = H, (H3LCl)-Cl-2, 2; R-1 = Bu-t, R-2 = H, R-3 = Cl, (H3LCl)-Cl-3, 3; R-1 = Bu-t, R-2 = CH3, R-3 = H, (H3LCl)-Cl-4, 4), were used to produce a novel series of ionic iron(III) complexes [H3Ln][FeX4] (n = 1, X = Cl, 5; n = 2, X = Cl, 6; n = 3, X = Cl, 7; n = 4, X = Cl, 8; n = 1, X = Br, 9; n = 3, X = Br, 10). All of the complexes were characterized by Raman spectroscopy and electrospray ionization mass spectrometry. Elemental analysis and X-ray crystallography were also used. All of the complexes were non-hygroscopic and air-stable, with five of them existing as solids (5, 7-10) and one as an oil (6) at room temperature. A preliminary catalytic study on the cross-coupling reactions of aryl Grignard reagents with primary and secondary alkyl halides bearing beta-hydrogens, revealed that all of the ionic iron(III) complexes exhibited good to excellent catalytic activity. Complexes 5, 6 and 8 exhibited optimal activity, whereas 7, 9 and 10 showed only moderate activity. Furthermore, by simply decanting the cross-coupling product in the ether layer, complexes 5 and 6 could be reused in at least seven successive runs without significant loss in catalytic activity.
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