Journal
DALTON TRANSACTIONS
Volume 41, Issue 19, Pages 5995-6002Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2dt12435a
Keywords
-
Categories
Funding
- German Science Foundation (DFG) [Vo829/6-1, SCHM 1389/5-1]
Ask authors/readers for more resources
The synthesis of a structurally optimized tribenzotriquinacene receptor 9 is described, which is extended by centrohexaindane moieties to give rise to a half-round concave ball bearing, with optimum shape complementarity towards C-60 fullerene. Spectroscopic investigations reveal that this novel host forms a 1 : 1 host-guest complex with C-60 with a complex stability constant of K-1 = 14 550 +/- 867 M-1, which is considerably higher than those reported for structurally related tribenzotriquinacene hosts reported previously. Both the suppression for binding of a second receptor (i.e. formation of a 2 : 1 host-guest complex) as well as the increase of complex stability of the 1 : 1 complex can be rationalized in terms of multiple additive van der Waals and p-p interactions between C-60 and the aromatic groups of the receptor, as revealed by DFT + D and force-field calculations. Combining results from spectroscopic and theoretical investigations leads to predictions in light of future receptor designs, which - apart from shape complementarity - will have to consider an optimized electronic match (i.e. partial charge transfer) between the receptor and the fullerene host.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available